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RAS Chemistry & Material ScienceЖурнал общей химии Russian Journal of General Chemistry

  • ISSN (Print) 0044-460X
  • ISSN (Online) 3034-5596

5-(2-pyridyl)tetrabenzoporphyrin and its complexes with zinc, cobalt, copper and iron. synthesis, spectral, electrochemical and electrocatalytic properties

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PII
10.31857/S0044460X23070168-1
DOI
10.31857/S0044460X23070168
Publication type
Article
Status
Published
Authors
E. I Mayorova
  • Affiliation: Ivanovo State University of Chemistry and Technology
M. V. Kozlova
  • Affiliation: Ivanovo State University of Chemistry and Technology
Volume/ Edition
Volume 93 / Issue number 7
Pages
1114-1123
Abstract
The interaction of phthalimide with 2-picoline in the presence of zinc oxide synthesized 3-(pyridin-2-ylmethylene)isoindolin-1-one. Heating its mixture with an excess of phthalimide and zinc acetate leads to the formation of zinc 5-(2-pyridyl)tetrabenzoporphyrinate, which, upon treatment with acid, is converted to 5-(2-pyridyl) tetrabenzoporphyrin. The latter, when interacting with cobalt(II), copper(II), and iron(III) chlorides in DMF, forms the corresponding metal complexes. The composition and structure of the obtained compounds were confirmed by mass spectrometry, vibrational, 1H NMR, and electron spectroscopy. The results of quantum-chemical calculations of complexes by the DFT method are presented. A correlation is established between the energy gap between the frontier orbitals and the positions of the first bands in the electronic absorption spectra. All the synthesized tetrabenzoporphyrins exhibit catalytic activity in the electroreduction of oxygen, the highest activity being exhibited by cobalt and copper complexes.
Keywords
2-пиколин мезо-пиридилтетрабензопорфирин металлокомплекс спектральные свойства квантово-химические расчеты электрохимия электрокатализ
Date of publication
17.09.2025
Year of publication
2025
Number of purchasers
0
Views
13

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