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RAS Chemistry & Material ScienceЖурнал общей химии Russian Journal of General Chemistry

  • ISSN (Print) 0044-460X
  • ISSN (Online) 3034-5596

Synthesis and Spectral Fluorescence Properties of Mg(II)-Porphyrins

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PII
S3034559625090093-1
DOI
10.7868/S3034559625090093
Publication type
Article
Status
Published
Authors
S. V. Zvezdina
  • Affiliation: G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences
N. V. Chizhova
  • Affiliation: G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences
A. E. Likhonina
  • Affiliation: G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences
N. Zh. Mamardashvili
  • Affiliation: G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences
Volume/ Edition
Volume 95 / Issue number 9-10
Pages
434-445
Abstract
Mg(II)-5,15-diphenylporphyrin, Mg(II)-5,10,15,20-tetraphenylporphyrin, Mg(II)-2,3,7,8,12,13,17,18-octaethylporphyrin and Mg(II)-5,10,15,20-tetra-(pentafluorophenyl)porphyrin were obtained using the coordination reaction of the corresponding porphyrins with magnesium acetate in a boiling dimethylformamide–ethylene glycol mixture. The complexation of β-octachloro-5,10,15,20-tetra(pentafluorophenyl)porphyrin with magnesium acetate in dimethylformamide already at room temperature led to the formation of the corresponding Mg(II)-porphyrinate. A facile method for the preparation of magnesium complexes with magnesium chloride in dimethylformamide has been proposed as an example of the metal exchange reaction of Cd(II)-5,10,15,20-tetraphenylporphyrin and Cd(II)-2,3,7,8,12,13,17,18-octaethylporphyrin. The synthesized compounds were identified by UV-Vis, NMR spectroscopy, mass spectrometry and elemental analysis methods. The fluorescence properties of Mg-porphyrins in acetone have been studied. The values of fluorescence quantum yields and Stokes shifts of the studied compounds were calculated. The influence of the nature of substituents on the fluorescence characteristics of Mg-porphyrins was evaluated. The coordination reaction of β-octachloro-5,10,15,20-tetra(pentafluorophenyl)porphyrin with magnesium acetate in dimethylformamide was studied by spectrophotometric method. The kinetic parameters were calculated and the stoichiometric mechanism of the studied reaction has been proposed.
Keywords
порфирины порфиринаты Mg(II) и Cd(II) ацетаты и хлориды магния реакция комплексообразования металлообмена спектрально-флуоресцентные свойства
Date of publication
21.12.2025
Year of publication
2025
Number of purchasers
0
Views
48

References

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