- PII
- 10.31857/S0044460X24110049-1
- DOI
- 10.31857/S0044460X24110049
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume 94 / Issue number 11-12
- Pages
- 1095-1101
- Abstract
- Extraction of microquantities of lanthanides(III) from HNO3 solutions with solutions of bis[N-octyl-N-(2-diphenylphosphinylethyl)]amide of diglycolic acid [Ph2P(O)CH2CH2N(Oct)C(O)CH2]2O in organic solvents was studied. Stoichiometry of extracted complexes was determined, influence of extractant structure, nature of organic diluent and composition of aqueous phase on efficiency and selectivity of extraction of lanthanide(III) ions into organic phase was considered. It was shown that modification of diglycolamides by introduction of additional coordinating groups CH2CH2P(O)Ph2 into their molecule via amide nitrogen atom leads to increase of extraction of lanthanides(III) from neutral and weakly acidic nitrate media when using a mixture of n-dodecane with tributylphosphate as a solvent.
- Keywords
- экстракция лантаниды(III) диамиды дигликолевой кислоты
- Date of publication
- 17.09.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 16
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