RAS Chemistry & Material ScienceЖурнал общей химии Russian Journal of General Chemistry

  • ISSN (Print) 0044-460X
  • ISSN (Online) 3034-5596

Synthesis of Copper-Nickel Bimetallic Nanoparticles by Caprylate Reduction in Benzyl Alcohol

PII
10.31857/S0044460X24030151-1
DOI
10.31857/S0044460X24030151
Publication type
Article
Status
Published
Authors
Volume/ Edition
Volume 94 / Issue number 3
Pages
450-460
Abstract
Based on the process of joint reduction of copper and nickel caprylates in benzyl alcohol at 185°C, a simple method for the synthesis of bimetallic copper and nickel nanoparticles was developed. The prepared bimetallic nanoparticles may be of interest for creating new compositions of electrically conductive inks and pastes for 2D and 3D printing. The resulting nanoparticles were characterized by X-ray phase analysis, scanning and transmission electron microscopy in combination with energy-dispersive X-ray spectroscopy. The prepared copper and nickel nanoparticles are single- or two-phase bimetallic solid solutions of various compositions. The effect of the phase composition of bimetallic powders on their resistance to oxidation was studied. It was shown that an increase in the nickel content in the composition leads to a decrease in the degree of nanoparticles oxidation. The proposed method is one-step, does not require the use of additional stabilizers and reducing agents, the synthesis is carried out in one-pot and is easily scalable. The method can also be used to obtain other bi- and polymetallic nanoparticles.
Keywords
никель медь биметаллические наночастицы карбоксилаты бензиловый спирт восстановление
Date of publication
16.09.2025
Year of publication
2025
Number of purchasers
0
Views
13

References

  1. 1. Wu W. // Nanoscale. 2017. Vol. 9. P. 7342. doi 10.1039/C⁷NR01604B
  2. 2. Huang Q., Zhu Y. // Adv. Mater. Technol. 2019. Vol. 4. N 5. P. 1. doi 10.1002/admt.201970029
  3. 3. Nanotechnology for food packaging. Materials, processing technologies, and safety issues / Eds M. Cerqueira, J. Lagaron, L. Castro, A. Vicente. Amsterdam: Elsevier, 2018. 332 p.
  4. 4. Rao V.K., Abhinav K.V., Karthik P.S., Singh S.P. // RSC Adv. 2015. Vol. 5. P. 77760. doi 10.1039/C⁵ra12013f
  5. 5. Magdassi S., Grouchko M., Kamyshny A. // Materials. 2010. Vol. 3. N 9. P. 4626. doi 10.3390/ma3094626
  6. 6. Songping W. // Microelectronics J. 2007. Vol. 38. N 1. P. 41. doi 10.1016/j.mejo.2006.09.013
  7. 7. Songping W., Li J., Jing N., Zhenou Z., Song L. // Intermetallics. 2007. Vol. 15. N 10. P. 1316. doi 10.1016/ j.intermet.2007.04.001
  8. 8. Sharma M.K., Qi D., Buchner R.D., Scharmach W.J., Papavassiliou V., Swihart M.T. // ACS Appl. Mater. Interfaces. 2014. Vol. 6. N 16. P. 13542. doi 10.1021/am5026853
  9. 9. Seemala B., Cai C.M., Kumar R., Wyman C.E., Christopher Ph. // ACS Sustain. Chem. Eng. 2018. Vol. 6. N 2. P. 2152. doi 10.1021/acssuschemeng.7b03572
  10. 10. Pastor-Pérez L., Gu S., Sepúlveda-Escribano A., Rein T.R. // Int. J. Hydrog. Energy. 2019. Vol. 44. N 8. P. 4011. doi 10.1016/j.ijhydene.2018.12.127
  11. 11. Meneses-Brassea B.P., Borrego E.A., Blazer D.S., Sanad M.F., Pourmiri S., Gutierrez D.A., Varela-Ramirez A., Hadjipanayis G.C., El-Gendy A.A. // Nanomaterials. 2020. Vol. 10. N 10. P. 1988. doi 10.3390/nano10101988
  12. 12. Ban I., Stergar J., Drofenik M., Ferk G., Makovec D. // J. Magn. Magn. Mater. 2011. Vol. 323. N 17. P. 2254. doi 10.1016/j.jmmm.2011.04.004
  13. 13. Toshima, N., Yonezawa, T. // New J. Chem. 1998. Vol. 22. N 11. P. 1179. https://doi.org/10.1039/A805753B
  14. 14. Ferk G., Stergar J., Makovec D., Hamler A., Jaglicic Z., Drofenik M., Ban I. // J. Alloys Compd. 2015. Vol. 648. N 5. P. 53. doi 10.1016/j.jallcom.2015.06.067
  15. 15. Stergar J., Ferk G., Ban I., Drofenik M., Hamler A., Jagodic M., Makovec D. // J. Alloys Compd. 2013. Vol. 576. P. 220. doi 10.1016/j.jallcom.2013.04.130
  16. 16. Wen M., Liu Q.Y., Wang Y.F., Zhu Y.Z., Wu Q.S. // Colloids Surf. (A). 2008. Vol. 318. P. 238. doi 10.1016/ j.colsurfa.2007.12.041
  17. 17. Пугачев В.М., Захаров Ю.А., Васильева О.В., Карпушкина Ю.В., Додонов В.Г. // Химия в интересах устойчивого развития. 2015. Т. 23. С. 169. doi 10.15372/KhUR²0150211
  18. 18. Fiévet F., Ammar-Merah S., Brayner R., Chau F., Giraud M., Mammeri F., Peron J., Piquemal J.-Y., Sicard L., Viau G. // Chem. Soc. Rev. 2018. Vol. 47. P. 5187. doi 10.1039/C⁷CS00777A
  19. 19. Parimaladevi R., Parvathi V.P., Lakshmi S.S., Umadev M. // Mater. Lett. 2018. Vol. 211. P. 82. doi 10.1016/ j.matlet.2017.09.097
  20. 20. Bonet F., Grugeon S., Dupont L., Herrera Urbina R., Guery C., Tarascon J.M. // J. Solid State Chem. 2003. Vol. 172. P. 111. doi 10.1016/S0022-4596(02)00163-9
  21. 21. Niederberger M., Bartl M.H., Stucky G.D. // J. Am. Chem. Soc. 2002. Vol. 124, N 46. P. 13642–13643. https://doi.org/10.1021/ja027115i
  22. 22. Ляхов Н.З., Юхин Ю.М., Тухтаев Р.К., Мищенко К.В., Титков А.И., Логутенко О.А. // Химия в интересах устойчивого развития. 2014. Т. 22. № 4. С. 409.
  23. 23. Юхин Ю.М., Титков А.И., Логутенко О.А., Мищенко К.В., Ляхов Н.З. // ЖОХ. 2017. Т. 87. № 12. С. 2057; Yukhin Yu.M., Titkov A.I., Logutenko O.A., Mishchenko K.V., Lyakhov N.Z. // Russ. J. Gen. Chem. 2017. Vol. 87. N 12. P. 2870. doi 10.1134/S1070363217120180
  24. 24. Юхин Ю.М., Логутенко О.А., Титков А.И., Ляхов Н.З. // Хим. технол. 2016. Т. 17. № 7. С. 314; Yukhin Yu.M., Logutenko O.A., Titkov A.I., Lyakhov N.Z. // Theor. Found. Chem. Eng. 2017. Vol. 51. N 5. P. 809. doi 10.1134/S0040579517050232
  25. 25. Титков А.И., Логутенко О.А., Булина Н.В., Юхин Ю.М., Ляхов Н.З. // Хим. технол. 2016. Т. 17. № 5. С. 202; Titkov A.I., Logutenko O.A., Bulina N.V., Yukhin Y.M., Lyakhov N.Z. // Theor. Found. Chem. Eng. 2017. Vol. 51. N 4. P. 557. doi 10.1134/S004057951704014
  26. 26. Titkov A.I., Logutenko O.A., Vorobyov A.M., Gerasimov E.Yu., Shundrina I.K., Bulina N.V., Lyakhov N.Z. // Colloids Surf. (A). 2019. Vol. 577. P. 500. doi 10.1016/ j.colsurfa.2019.06.008
  27. 27. Tsybulya S.V., Cherepanova S.V., Soloviyova L.P. // J. Struct. Chem. 1996. Vol. 37, N 2. 332. https://doi.org/10.1007/bf02591064
  28. 28. Пирсон У.Б. Кристаллохимия и физика металлов и сплавов. М.: Мир, 1977. T. 1. 419 c.
QR
Translate

Индексирование

Scopus

Scopus

Scopus

Crossref

Scopus

Higher Attestation Commission

At the Ministry of Education and Science of the Russian Federation

Scopus

Scientific Electronic Library