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RAS Chemistry & Material ScienceЖурнал общей химии Russian Journal of General Chemistry

  • ISSN (Print) 0044-460X
  • ISSN (Online) 3034-5596

Chemical stability of Pb[(UO2)2O2(OH)2](H2O) and Pb2[(UO2)5O6(OH)2](H2O)2 compounds in aqueous solutions

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PII
10.31857/S0044460X23100104-1
DOI
10.31857/S0044460X23100104
Publication type
Article
Status
Published
Authors
O. V Nipruk
  • Affiliation: Lobachevsky State University of Nizhni Novgorod
M. V. Kozlova
  • Affiliation: Lobachevsky State University of Nizhni Novgorod
Volume/ Edition
Volume 93 / Issue number 10
Pages
1621-1632
Abstract
The chemical stability of Pb[(UO2)2O2(OH)2](H2O) and Pb2[(UO2)5O6(OH)2](H2O)2 compounds in aqueous solutions was studied. The acid-base boundaries of the existence of these compounds in aqueous solutions were established, the hydrolysis products were identified, and the solubility was determined. Based on the data obtained, the equilibrium constants of dissolution reactions, the Gibbs functions of the formation and dissolution of Pb[(UO2)2O2(OH)2](H2O) and Pb2[(UO2)5O6(OH)2](H2O)2, were calculated, the solubility curves of the compounds under study, and the phase diagrams of U(VI) and Pb(II) in saturated aqueous solutions and in equilibrium solid phases were calculated.
Keywords
уран свинец PbUOH-соединения водный раствор растворимость произведение растворимости
Date of publication
15.10.2023
Year of publication
2023
Number of purchasers
0
Views
30

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