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RAS Chemistry & Material ScienceЖурнал общей химии Russian Journal of General Chemistry

  • ISSN (Print) 0044-460X
  • ISSN (Online) 3034-5596

Mn(II)-cu(I) hybrid complex based on 1,3,5-tris(diphenylphosphinyl)benzene

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PII
10.31857/S0044460X23070181-1
DOI
10.31857/S0044460X23070181
Publication type
Article
Status
Published
Authors
M. V. Kozlova
  • Affiliation: Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
A. N. Turanov
  • Affiliation: A.N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Volume/ Edition
Volume 93 / Issue number 7
Pages
1132-1138
Abstract
The reaction of 1,3,5-tris(diphenylphosphinyl)benzene (L) with MnI2 in the presence of CuI (wet MeCN, 25°C, 30 min) leads to the formation of a complex [MnL4(H2O)2][Cu5I7(CH3CN)]·7MeCN with yield of 72%. The Mn2+ ion of this complex has a distorted Mn@O6 octahedral environment formed by four L ligands and two coordinated water molecules. The [Cu5I7(CH3CN)]2- anion has an unprecedented structure of the {Cu5I7} backbone, which includes five copper atoms bound by bridging iodide ions (µ2, µ3, µ4), as well as four short Cu···Cu contacts (
Keywords
марганец(II) медь(I) фосфиноксиды координационные соединения марганца(II) фосфоресценция
Date of publication
17.09.2025
Year of publication
2025
Number of purchasers
0
Views
14

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