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RAS Chemistry & Material ScienceЖурнал общей химии Russian Journal of General Chemistry

  • ISSN (Print) 0044-460X
  • ISSN (Online) 3034-5596

Complex of Mn(II) Perchlorate with (2-Methylenepropane-1,3-diyl)bis(diphenylphosphine Oxide): Synthesis, Structure, and Double Luminescence

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PII
10.31857/S0044460X23020129-1
DOI
10.31857/S0044460X23020129
Publication type
Article
Status
Published
Authors
M. V. Kozlova
  • Affiliation: Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences
A. N. Turanov
  • Affiliation: A.N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Volume/ Edition
Volume 93 / Issue number 2
Pages
266-272
Abstract
The reaction of Mn(ClO4)2·6H2O with (2-methylenepropan-1,3-diyl)bis(diphenylphosphine oxide) (L) in a methanol medium yielded a previously unknown complex [MnL2(MeOH)2](ClO4)2. According to X-ray diffraction data, its Mn2+ ion has a distorted octahedral environment formed by two chelate L ligands and two coordinated methanol molecules. At 298 K, this complex exhibits low-intensity dual luminescence, the low-energy component of which is attributed to Mn2+-centered phosphorescence, and the high-energy component is assigned to intraligand fluorescence.
Keywords
комплексы марганца(II) фосфиноксиды фосфоресценция двойная люминесценция
Date of publication
17.09.2025
Year of publication
2025
Number of purchasers
0
Views
12

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