RAS Chemistry & Material ScienceЖурнал общей химии Russian Journal of General Chemistry

  • ISSN (Print) 0044-460X
  • ISSN (Online) 3034-5596

Extraction and sorption recovery of rhenium(VII) using oligodentate β-аminophosphoryl compounds

PII
10.31857/S0044460X24040053-1
DOI
10.31857/S0044460X24040053
Publication type
Article
Status
Published
Authors
Volume/ Edition
Volume 94 / Issue number 4
Pages
511-518
Abstract
The interphase distribution of microquantities of ReO4 between aqueous solutions of mineral acids and solutions of oligodentate β-aminophosphoryl compounds in organic solvents was studied. The stoichiometry of the extracted complexes was determined, the influence of the concentration of HClO4, HNO3, HCl and H2SO4 in the aqueous phase, the structure of the extractant and the nature of the organic solvent on the efficiency of the transition of ReO4 ions into the organic phase was considered. The possibility of selective extraction and concentration of Re(VII) with a complexing sorbent obtained by non-covalent attachment of tris[bis(2-diphenylphosphorylethyl)aminoethyl]amine on the surface of the macroporous polymer Amberlite XAD7HP was demonstrated.
Keywords
экстракция сорбция рений(VII) аминофосфорильные соединения
Date of publication
17.09.2025
Year of publication
2025
Number of purchasers
0
Views
13

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