- PII
- 10.31857/S0044460X23010171-1
- DOI
- 10.31857/S0044460X23010171
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume 93 / Issue number 1
- Pages
- 146-152
- Abstract
- The synthesis of CoNPs cobalt nanoparticles by the method of polyol- process was proposed, which consists in a high-temperature synthesis of polymer-stabilized metal nanoparticles in a matrix of a fourth-generation hyperbranched polyester polyol. Branched polyester polyol acts as both a reducing agent and a stabilizer at the same time. It has been found that the reduction of the precursor CoCl2 with a hyperbranched polyester polyol occurs at 210°C. The introduction of NaOH into the reaction mixture makes it possible to lower the synthesis temperature by 50°C and leads to a change in the mechanism of in situ ripening CoNPs from the digestive mechanism to direct Ostwald ripening.
- Keywords
- сверхразветвленный полиэфирополиол наночастицы кобальта полиольный метод
- Date of publication
- 17.09.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 14
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